荻原研究室

九州大学 中央分析センター/大学院総合理工学府 総合理工学専攻 材料理工学メジャー

Papers

2025

  1. Isomeric Effects of Al13 Keggin Clusters as Catalyst Support on Oxidation Reactions
    A. Tateno‡, W. Zhou‡, A. Gao, Z. Weng, N. Ogiwara*, and S. Uchida* (‡equal contribution)
    Nanoscale, 2025, 17 (43), 25010–25014.
    DOI: 10.1039/D5NR03696H
  2. The Nature of Structural Defects in ZIF-8 Revealed with 1H and 31P MAS NMR and X-Ray Absorption Spectroscopy
    A. A. Gabrienko,* S. Chaemchuen, Z. Kou, N. Ogiwara, H. Kitagawa, A. E. Khudozhitkov, A. G. Stepanov, D. I. Kolokolov,* F. Verpoort*
    Angew. Chem. Int. Ed., 2025, 64 (2), e202414823.
    DOI: 10.1002/anie.202414823
  3. Flexible Organic–inorganic Hybrid Crystals of Tin (iv) Chloride and Naphthalenediimide: Exploring Elasticity, Mechanochromism, and Photothermal Conversion
    S. Kusumoto*, S. Masuda, R. Suzuki, M. Tachibana, M. Shimabukuro, M. Kobayashi, N. Ogiwara, S. Uchida, T. Fukui, Y. Tsuji, M. Okamura, S. Hikichi, Y. Kim, Y. Koide*
    J. Mater. Chem. C, 2025, 13 (17), 8470–8478.
    DOI: 10.1039/D5TC00891C
  4. Solid-state Stepwise Temperature-programmable Synthesis of Bioinspired Fe-N-C Oxygen Reduction Electrocatalyst Featuring Fe-N5 Configuration
    W. Sang, S. Chaemchuen, L. Zhang, Z. Wang, X. Li, C. A. Nagasaka, M. Xiong, N. Ogiwara, C. Chen, Z. Wang, J. Zhang, F. Verpoort, S. Mu, Z. Kou,* T. Wang*
    Nano Res., 2025, 18 (3), 94907245.
    DOI: 10.26599/NR.2025.94907245

2024

  1. Dynamics of Linkers in Metal–Organic Framework Glasses
    A. E. Khudozhitkov, N. Ogiwara*, M. Donoshita, H. Kobayashi, A. G. Stepanov, D. I. Kolokolov*, H. Kitagawa*
    J. Am. Chem. Soc., 2024, 146 (19), 12950–12957.
    DOI: 10.1021/jacs.3c13156
  2. Reduction-Induced Uptake of Cs+ in Metal–Organic Frameworks Loaded with Polyoxometalates
    C. A. Nagasaka, N. Ogiwara*, S. Kobayashi, S. Uchida*
    Small, 2024, 20 (17), 23007004.
    DOI: 10.1002/smll.202307004
  3. Cationic Al Oxo-hydroxide Clusters: Syntheses, Molecular Structures, and Functional Applications
    N. Ogiwara, W. Zhou, S. Uchida*
    Chem. Sci., 2024, 15 (46), 19212–19224.
    DOI: 10.1039/D4SC05707D
    Perspective
  4. Pore Design of POM@MOF Hybrids for Enhanced Methylene Blue Capture
    S. Miyazaki, N. Ogiwara*, C. A. Nagasaka, K. Takiishi, M. Inada, S. Uchida*
    Bull. Chem. Soc. Jpn,, 2024, 97 (10), uoae105.
    DOI: 10.1093/bulcsj/uoae105
  5. Assembled Structures and Electrical Conductivities of Salts Comprised of Cationic Sandwich Complexes and Polyoxometalates
    R. Inoue, N. Ogiwara, S. Uchida, T. Mochida*
    Inorg. Chem., 2024, 63 (40), 18830–18837.
    DOI: 10.1021/acs.inorgchem.4c02890
  6. Tuning Proton Conduction by Staggered Arrays of Polar Preyssler-Type Oxoclusters
    T. Iwano, D. Akutsu, H. Ubukata, N. Ogiwara, Y. Kikukawa, S. Wang, L. Yan, H. Kageyama, S. Uchida*
    J. Am. Chem. Soc., 2024, 146 (38), 26113–26120.
    DOI: 10.1021/jacs.4c06743
  7. Simultaneous Productions of High-purity Calcium Carbonate and Amorphous Nanosized Silica-Rich Gel from Waste Concrete Powder by Alkaline Treatment and Carbonation
    L. Liu*, G. Ou, L. Xu, N. Ogiwara, S. Uchida, H. Yang*, Y. Sakai
    J. Environ. Manag., 2024, 372, 123319.
    DOI: 10.1016/j.jenvman.2024.123319

2023

  1. Metal–Oxo-Cluster-Based Crystals as Solid Catalysts
    N. Ogiwara, S. Uchida*
    Chem Catal., 2023, 3 (7), 100607.
    DOI: 10.1016/j.checat.2023.100607
    Review Article
  2. Proton Conduction in Ionic Crystals Based on Polyoxometalates
    N. Ogiwara, T. Iwano, T. Ito, S. Uchida*
    Coord. Chem. Rev., 2023, 462, 214524.
    DOI: 10.1016/j.ccr.2022.214524
    Review Article
  3. A Redox-Active Inorganic Crown Ether Based on a Polyoxometalate Capsule
    N. Tamai, N. Ogiwara, E. Hayashi, K. Kamata, T. Misawa, T. Ito,T. Kojima, M. Segado, E. Petrus, C. Bo, S. Uchida*
    Chem. Sci., 2023, 14 (20), 5453–5459.
    DOI: 10.1039/D3SC01077E
  4. Size-Controlled Synthesis of Luminescent Few-Atom Silver Clusters via Electron Transfer in Isostructural Redox-Active Porous Ionic Crystals
    N. Haraguchi, N. Ogiwara, Y. Kumabe, S. Kikkawa, S. Yamazoe, T. Tachikawa*, S. Uchida*
    Small, 2023, 19 (23), 2300743 .
    DOI: 10.1002/smll.202300743
  5. Bismuth Substitution in HSbOI with Positively-Charged Oxide Clusters
    Y. Watanabe, T. Goto, J. Xia, N. Ogiwara, H. Tabe, S. Horike, Y. Noda, S. Uchida, H. Kageyama*
    Chem. Lett., 2023, 52 (6), 430–433.
    DOI: 10.1246/cl.230077
  6. Surpassing Pt Hydrogen Production from {200} Facet-Riched Polyhedral Rh2P Nanoparticles by One-Step Synthesis
    H. Xin, L.Sun, Y. Zhao, Z. Dai, Q. Luo, S. Guo, D. Li, Y. Chen, N. Ogiwara, H. Kitagawa, B. Huang*, F. Ma*
    Appl. Catal. B, 2023, 303, 122645.
    DOI: 10.1016/j.apcatb.2023.122645
  7. Role of Thermo-alkaline-oxidized Kraft Lignin Aided by Concrete Waste as a Potential Reinforcement Material in Botanical Concrete
    R. Wei*, Y. Sakai, N. Ogiwara, S. Uchida,
    Constr. Build. Mater., 2023, 406, 133434.
    DOI: 10.1016/j.conbuildmat.2023.133434
  8. Direct Synthesis of Eco-friendly Construction Material from Low-quality Sand via Sol-gel Method
    P. Qiu*, Y. Sakai, Y. Tamura, N. Ogiwara, S. Uchida,
    Constr. Build. Mater., 2023, 392, 131906.
    DOI: 10.1016/j.conbuildmat.2023.131906

2022

  1. Vanadium-Substituted Polycationic Al-Oxo Cluster in a Porous Ionic Crystal Exhibiting Lewis Acidity
    W. Zhou, N. Ogiwara*, Z. Weng, C. Zhao, L. Yan, Y. Kikukawa, S. Uchida*
    Chem. Commun., 2022, 58 (90), 12548–12551.
    DOI: 10.1039/D2CC03545F
  2. Oxygen Evolution Reaction Driven by Charge Transfer from a Cr Complex to Co-Containing Polyoxometalate in a Porous Ionic Crystal
    Y. Shimoyama, N. Ogiwara, Z. Weng, S. Uchida*
    J. Am. Chem. Soc., 2022, 144 (7), 2980–2986.
    DOI: 10.1021/jacs.1c10471
  3. Basicity of Isostructural Porous Ionic Crystals Composed of Nb/Ta-Substituted Keggin-Type Polyoxotungstates
    Z. Weng, N. Ogiwara, D. Yokogawa, T. Kitao, Y. Kikukawa, S. Uchida*
    Dalton Trans., 2022, 51 (21), 8186–8191.
    DOI: 10.1039/D2DT00478J
  4. Polyoxocationic Antimony Oxide Cluster with Highly Acidic Protons
    Y. Watanabe, K. Hyeon-Deuk, T. Yamamoto, M. Yabuuchi, O. M. Karakulina, Y. Noda, T. Kurihara, I. Chang, M. Higashi, O. Tomita, C. Tassel, D. Kato, J. Xia, T. Goto, C. M. Brown, Y. Shimoyama, N. Ogiwara, J. Hadermann, A. M. Abakumov, S. Uchida*, R. Abe*, H. Kageyama*
    Sci. Adv., 2022, 8 (24), eabm5379.
    DOI: 10.1126/sciadv.abm5379
  5. Syntheses, Polymorphic Transformations, and Functions of Ionic Crystals Based on Mononuclear Bismuth(III) Complexes and Polyoxometalates
    T. Iwano, D. Akutsu, Z. Weng, N. Ogiwara, S. Uchida*
    ChemNanoMat, 2022, 8 (5), e202100479.
    DOI: 10.1002/cnma.202100479
  6. Bonding Mechanism of Botanical Concrete: Microstructural Changes between Waste Concrete Powder and Wood
    R. Wei*, Y. Sakai, N. Ogiwara, S. Uchida
    J. Clean. Prod., 2022, 378, 134505.
    DOI: 10.1016/j.jclepro.2022.134505
  7. Phase Control of Solid-solution Nanoparticles Beyond the Phase Diagram for Enhanced Catalytic Property
    D. Wu*, K. Kusada*, S. Aspera, H. Nakanishi, Y. Chen, O. Seo, C. Song, J. Kim, S. Hiroi, O. Sakata, T. Yamamoto, S. Matsumura, Y. Nanba, M. Koyama, N. Ogiwara, S. Kawaguchi, Y. Kubota, H. Kitagawa*
    ACS Mater. Au, 2022, 2 (2), 110–116 .
    DOI: 10.1021/acsmaterialsau.1c00048

2021

  1. Integrating Molecular Design and Crystal Engineering Approaches in Non-humidified Intermediate-temperature Proton Conductors Based on a Dawson-type Polyoxometalate and Poly(ethylene glycol) Derivatives
    N. Ogiwara,‡ M. Tomoda,‡ S. Miyazaki, Z. Weng, H. Takatsu, H. Kageyama, T. Misawa, T. Ito, S. Uchida*, (‡equal contribution)
    Nanoscale, 2021, 13 (17), 8049–8057.
    DOI: 10.1039/D1NR01220G
  2. Isomeric Effects on the Acidity of Al13 Keggin Clusters in Porous Ionic Crystals
    W. Zhou, N. Ogiwara, Z. Weng, N. Tamai, C. Zhao, L. Yan, S. Uchida*
    Chem. Commun., 2021, 57 (71), 8893–8896.
    DOI: 10.1039/D1CC03600A
  3. Incorporating Highly-basic Polyoxometalate Anions Comprising Nb or Ta into Nanoscale Reaction Fields of Porous Ionic Crystals
    Z. Weng, N. Ogiwara, T. Kitao, Y. Kikukawa, Y. Gao, L. Yan, S. Uchida*
    Nanoscale, 2021, 13 (44), 18451–18457.
    DOI: 10.1039/D1NR04762K
  4. Fabrication of Integrated Copper-Based Nanoparticles/Amorphous Metal–Organic Framework by Facile Spray-Drying Method: Highly Enhanced CO2 Hydrogenation Activity for Methanol Synthesis
    Y. Mitsuka*, N. Ogiwara, M. Mukoyoshi, H. Kitagawa*, T. Yamamoto, T. Toriyama, S. Matsumura, M. Haneda, S. Kawaguchi, Y. Kubota, H. Kobayashi*
    Angew. Chem. Int. Ed., 2021, 60 (41), 22283–22288.
    DOI: 10.1002/anie.202110585
  5. Recording the Pt-beyond Hydrogen Production Electrocatalysis by Dirhodium Phosphide with an Overpotential of Only 4.3 mV in Alkaline Electrolyte
    H. Xin, Z. Dai, Y. Zhao, S. Guo, J. Sun, Q. Luo, P. Zhang, L. Sun, N. Ogiwara, H. Kitagawa, B. Huang*, F. Ma*
    Appl. Catal. B, 2021, 297, 120457.
    DOI: j.apcatb.2021.120457
  6. Ultrahigh Proton Conduction via Extended Hydrogen-Bonding Network in a Preyssler-Type Polyoxometalate-Based Framework Functionalized with a Lanthanide Ion
    T. Iwano, K. Shitamatsu, N. Ogiwara, M. Okuno, Y. Kikukawa, S. Ikemoto, S. Shirai, S. Murasugu, P. Waddell, R. J. Errington, M. Sadakane*, S. Uchida*
    ACS Appl. Mater. Interfaces, 2021, 13 (16), 19138–19147.
    DOI: 10.1021/acsami.1c01752
  7. Formation of Mixed-Valence Luminescent Silver Clusters via Cation-Coupled Electron-Transfer in a Redox-Active Ionic Crystal Based on a Dawson-type Polyoxometalate with Closed Pores
    N. Haraguchi, T. Okunaga, Y. Shimoyama, N. Ogiwara, S. Kikkawa, S. Yamazoe, M. Inada, T. Tachikawa, S. Uchida*
    Eur. J. Inorg. Chem., 2021 (16), 1531–1535 .
    DOI: 10.1002/ejic.202100101

2020

  1. Ligand Functionalization-Controlled Activity of Metal–Organic Framework-Encapsulated Pt Nanocatalyst toward Activation of Water
    N. Ogiwara, H. Kobayashi*, M. Inukai, Y. Nishiyama, P. Concepción, F. Rey, H. Kitagawa*
    Nano. Lett., 2020, 20 (1), 426–432.
    DOI: 10.1021/acs.nanolett.9b04124
  2. Isostructural Mesoporous Ionic Crystals as a Tunable Platform for Acid Catalysis
    Y. Shimoyama, Z. Weng, N. Ogiwara, T. Kitao, Y. Kikukawa, S. Uchida*
    Dalton Trans., 2020, 49 (30), 10328–10333.
    DOI: 10.1039/D0DT01202E
  3. Probing Dynamics of Carbon Dioxide in a Metal–Organic Framework under High Pressure by High-Resolution Solid-State NMR
    M. Inukai*, T. Kurihara, Y. Noda, W. Jiang, K. Takegoshi, N. Ogiwara, H. Kitagawa, K. Nakamura
    Phys. Chem. Chem. Phys., 2020, 22 (26), 14465–14470.
    DOI: 10.1039/D0CP01216E
  4. Crystalline to Amorphous Transformation in Solid-Solution Alloy Nanoparticles Induced by Boron Doping
    K. Kobayashi, K. Kusada, D. Wu, N. Ogiwara, H. Kobayashi*, M. Haruta, H. Kurata, S. Hiroi, O. Seo, C. Song, Y. Chen, J. M. Kim, A. Tayal, O. Sakata, K. Ohara, T. Honma, H. Kitagawa*
    Chem. Commun., 2020, 56 (85), 12941–12944.
    DOI: 10.1039/D0CC05418F

2019

  1. The First Study on the Reactivity of Water Vapor in Metal–Organic Frameworks with Platinum Nanocrystals
    N. Ogiwara, H. Kobayashi*, P. Concepción, F. Rey, H. Kitagawa*
    Angew. Chem. Int. Ed. , 2019, 58 (34), 11731–11736.
    DOI: 10.1002/anie.201905667
  2. The Effect of Amorphization on the Molecular Motion of the 2-Methylimidazolate Linkers in ZIF-8
    N. Ogiwara, D. I. Kolokolov*, M. Donoshita, H. Kobayashi, S. Horike, A. G. Stepanov, H. Kitagawa*
    Chem. Commun., 2019, 55 (42), 5906–5909.
    DOI: 10.1039/C9CC02673H
  3. Coating of 2D Flexible Metal–Organic Frameworks on Metal Nanocrystals
    N. Ogiwara, H. Kobayashi*, K. Kobayashi, T. Yamamoto, T. Toriyama, S. Matsumura, H. Kitagawa*
    Chem. Lett., 2019, 48 (2), 173–176.
    DOI: 10.1246/cl.180931
  4. Charge Transfer Dependence on CO2 Hydrogenation Activity to Methanol in Cu Nanoparticles Covered with Metal–Organic Framework Systems
    H. Kobayashi*, J. M Taylor, Y. Mitsuka, N. Ogiwara, T. Yamamoto, T. Toriyama, S. Matsumura, H. Kitagawa*
    Chem. Sci., 2019, 10 (11), 3289–3294.
    DOI: 10.1039/C8SC05441J
  5. Missing-Linker Metal-organic Frameworks for Oxygen Evolution Reaction
    Z. Xue, K. Liu, Q. Liu, Y. Li, M. Li, C. Su, N. Ogiwara, H. Kobayashi, H. Kitagawa, M. Liu*, G. Li*
    Nat. Commun., 2019, 10 (27), 5048.
    DOI: 10.1038/s41467-019-13051-2
  6. Solid-Solution Alloy Nanoparticles of a Combination of Immiscible Au and Ru with A Large Gap of Reduction Potential and Their Enhanced Oxygen Evolution Reaction Performancey
    Q. Zhang, K. Kusada*, D. Wu, N. Ogiwara, T. Yamamoto, T. Toriyama, S. Matsumura, S. Kawaguchi, Y. Kubota, T. Honma, H. Kitagawa*
    Chem. Sci., 2019, 10 (19), 5133–5137.
    DOI: 10.1039/C9SC00496C
  7. Conductive Metal–Organic Framework Nanowires Array for Electrocatalytic Oxygen Evolution
    W. Li, Q. Li, J. Xie, N. Ogiwara, H. Jiang, H. Kitagawa, G. Xu*, Y. Wang*
    J. Mater. Chem. A, 2019, 7 (11), 10431–10438.
    DOI: 10.1039/C9TA02169H3

2018

  1. Sequence-Regulated Copolymerization Based on Periodic Covalent Positioning of Monomers Along One-dimensional Nanochannels
    S. Mochizuki, N. Ogiwara, M. Takayanagi, M. Nagaoka, S. Kitagawa, T. Uemura*
    Nat. Commun., 2018, 9, 329.
    DOI: 10.1038/s41467-017-02736-1
  2. Lanthanide Based Porous Coordination Polymers: Syntheses, Slow Relaxation of Magnetization and Magnetocaloric Effect
    C. Das, A. Upadhyay, K. Ansari, N. Ogiwara, T. Kitao, S. Horike*, M. Shanmugam*
    Inorg. Chem., 2018, 57 (11), 6584–6598.
    DOI: 10.1021/acs.inorgchem.8b00720

2017

  1. Imidazolium Cation Transportation in a 1-D Coordination Polymer
    W. Chen, N. Ogiwara, K. Kadota, K. Panyarat, S. Kitagawa*, S. Horike*
    Dalton Trans., 2017, 46 (33), 6584–6598.
    DOI: 10.1039/C7DT02625K
  2. Mechanical Alloying of Metal–Organic Frameworks
    T. Panda, S. Horike*, K. Hagi, N. Ogiwara, K. Kadota, T. Itakura, M. Tsujimoto, S. Kitagawa*
    Angew. Chem. Int. Ed., 2017, 56 (9), 2413–2417.
    DOI: 10.1002/anie.201612587

2016

  1. Fast Conduction of Organic Cations in Metal Sulfate Frameworks
    N. Ogiwara, M. Inukai, T. Itakura, S. Horike*, S. Kitagawa*
    Chem. Mater., 2016, 28 (11), 3968–3975.
    DOI: 10.1021/acs.chemmater.6b01284
  2. Crystal Engineering of a Family of Hybrid Ultramicroporous Materials Based upon Interpenetration and Dichromate Linkersy
    H. Scott,‡ N. Ogiwara,‡ K. Chen, D. Madden, T. Pham, K. Forrest, B. Space, S. Horike, J. Perry IV, S. Kitagawa*, M. J. Zaworotko*, (‡equal contribution)
    Chem. Sci., 2016, 7 (8), 5470–5476.
    DOI: 10.1039/C6SC01385F
  3. Encapsulating Mobile Proton Carriers into Structural Defects in Coordination Polymer Crystals: High Anhydrous Proton Conduction and Fuel Cell Application
    M. Inukai, S. Horike*, T. Itakura, R. Shinozaki, N. Ogiwara, D. Umeyama, S. Nagarkar, Y. Nishiyama, M. Malon, A. Hayashi, T. Ohhara, R. Kiyanagi, S. Kitagawa*
    J. Am. Chem. Soc., 2016, 138 (27), 8505–8511.
    DOI: 10.1021/jacs.6b03625
  4. Glass Formation of a Coordination Polymer Crystal for Enhanced Proton Conductivity and Material Flexibility
    W. Chen, S. Horike*, D. Umeyama, N. Ogiwara, T. Itakura, C. Tassel, Y. Goto, H. Kageyama, S. Kitagawa*
    Angew. Chem. Int. Ed., 2016, 55 (17), 5195–5200.
    DOI: 10.1002/anie.201600123
  5. Direct Synthesis of Hierarchically Porous Metal-Organic Frameworks with High Stability and Strong Brønsted Acidity: the Decisive Role of Hafnium in Efficient and Selective Fructose Dehydration
    Z. Hu, J. Lin, N. Ogiwara, A. Rodriguez, Y. Peng, Y. Wang, S. Horike*, D. Zhao*
    Chem. Mater., 2016, 28 (8), 2659–2667.
    DOI: 10.1021/acs.chemmater.6b00139
  6. A pH-Responsive Phase Transformation of a Sulfonated Metal–Organic Framework from Amorphous to Crystalline for Efficient CO2 Capture
    Z. Hu, J. Lin, N. Ogiwara, A. Rodriguez, Y. Peng, Y. Wang, S. Horike*, D. Zhao*
    CrystEngComm, 2016, 18 (16), 2803–2807.
    DOI: 10.1039/C6CE00369A

2015

  1. Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach
    M. Inukai, T. Fukushima, Y. Hijikata, N. Ogiwara, S. Horike*, S. Kitagawa*
    J. Am. Chem. Soc., 2015, 137 (38), 12183–12186.
    DOI: 10.1021/jacs.5b05413
  2. Formation of Foam-like Microstructural Carbon by Carbonization of Porous Coordination Polymer via Ligand-assisted Foaming Process
    K. Kongpatpanich, S. Horike*, Y. Fujiwara, N. Ogiwara, H. Nishihara, S. Kitagawa*
    Chem. Eur. J., 2015, 21 (38), 13278–13283.
    DOI: 10.1002/chem.201501988

2014

  1. Pressure-Induced Amorphization of a Dense Coordination Polymer and Its Impact on Proton Conductivity
    D. Umeyama, S.Horike*, C. Tassel, H. Kageyama, Y. Higo, K. Hagi, N. Ogiwara, S. Kitagawa*
    APL Mater., 2014, 2 (2), 124401.
    DOI: 10.1063/1.4898806